| Wessels | C H | | Member of the late Legislative Assembly, Orange River Colony
561 of 580 awards | Unknown |
| Wessels | Daniel H W | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
562 of 580 awards | Unknown |
| Whitaker | George | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
563 of 580 awards | Unknown |
| Whiteside | Peter | | Member of the late Legislative Assembly, Transvaal. Member of the Union Senate.
564 of 580 awards | Unknown |
| Wilcocks | Carl T H | | Member of the Union House of Assembly.
565 of 580 awards | Unknown |
| Williams | Edwin S | Lt Col | OC Kaffrarian Rifles
566 of 580 awards | Kaffrarian Rifles |
| Williams | H S | Captain | Dorset Regiment. DAA and QMG Pretoria District
567 of 580 awards | Dorsetshire Regiment |
| Willson | Charles G | | Member of the late Legislative Council, Natal
568 of 580 awards | Unknown |
| Wilmot | Alex | | Member of the late Legislative Council, Cape of Good Hope
569 of 580 awards | Unknown |
| Wiltshire | Henry | | Member of the Union House of Assembly.
570 of 580 awards | Unknown |
| Winter | H D | | Member of the late Legislative Assembly, Natal
571 of 580 awards | Unknown |
| Withinshaw | George S | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
572 of 580 awards | Unknown |
| Wolmarans | A D W | | Member of the late Legislative Council, Transvaal. Member of the Union Senate.
573 of 580 awards | Unknown |
| Woodhead | Henry | Lt Col | OC Duke of Edinburgh's Own Volunteer Rifles
574 of 580 awards | DEOVR |
| Woolls-Sampson | Aubrey | Colonel | Member of the late Legislative Assembly, Transvaal. Member of the Union House of Assembly.
575 of 580 awards | Unknown |
| Worthington | Edward S | Captain | RAMC, Medical Officer on the Staff of HRH Duke of Connaught
576 of 580 awards | Royal Army Medical Corps |
| Wybergh | Wilfred J | | Member of the late Legislative Assembly, Transvaal
577 of 580 awards | Unknown |
| Wylie | Jas S | Lt Col | OC Durban Light Infantry. Member of the late Legislative Assembly, Natal
578 of 580 awards | Durban Light Infantry |
| Wyndham | Hugh A | | Member of the Union House of Assembly.
579 of 580 awards | Unknown |
| Zondagh | Matthys P | | Member of the late House of Assembly, Cape of Good Hope
580 of 580 awards | Unknown |
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