| Van Boeschoten | Lady | | Mayoress of Pretoria during the Royal visit
521 of 580 awards | Unknown |
| Van Der Merwe | J E | | Member of the late Legislative Council, Transvaal
523 of 580 awards | Unknown |
| Van Der Merwe | Johannes A P | | Member of the Union House of Assembly.
522 of 580 awards | Unknown |
| Van Der Merwe | Willem J | | Member of the late House of Assembly, Cape of Good Hope
524 of 580 awards | Unknown |
| Van Der Post | Christiaan W H | | Member of the late Legislative Assembly, Orange River Colony
526 of 580 awards | Unknown |
| Van Eeden | Jacobus W | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
527 of 580 awards | Unknown |
| Van Heerden | Barend F J | | Member of the late Legislative Assembly, Transvaal
528 of 580 awards | Unknown |
| Van Heerden | Hercules C | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
529 of 580 awards | Unknown |
| Van Hulsteyn | W | | Member of the late Legislative Assembly, Transvaal
530 of 580 awards | Unknown |
| Van Niekerk | Christiaan A | | Member of the late Legislative Assembly, Orange River Colony. Member of the Union House of Assembly.
531 of 580 awards | Unknown |
| Van Riet | G J | | Member of the late Legislative Assembly, Orange River Colony
532 of 580 awards | Unknown |
| Van Rooy | Antonie C A | | Member of the late House of Assembly, Cape of Good Hope
533 of 580 awards | Unknown |
| Van Soelen | J N | | Member of the late Legislative Assembly, Orange River Colony
534 of 580 awards | Unknown |
| Van Vuuren | Lucas J | | Member of the late House of Assembly, Cape of Good Hope
535 of 580 awards | Unknown |
| Van Zyl | Hendrick S | | Member of the late House of Assembly, Cape of Good Hope
536 of 580 awards | Unknown |
| Van Zyl | Hermanus C | | Member of the late Legislative Council, Cape of Good Hope
537 of 580 awards | Unknown |
| Van Zyl | Izaak J | | Member of the late Legislative Council, Cape of Good Hope
538 of 580 awards | Unknown |
| Van Zyl | Willem J | | Member of the late House of Assembly, Cape of Good Hope
539 of 580 awards | Unknown |
| Vanderplank | William A | Lt Col | OC Zululand Mounted Rifles
525 of 580 awards | Zululand Mounted Rifles |
| Venter | Jan A | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
540 of 580 awards | Unknown |
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